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Self-testing has been established as a major approach for quantum device certification based on experimental statistics with minimal assumptions. However, despite more than 20 years of research effort, most of the self-testing protocols are restricted to spatial scenarios (Bell scenarios), without many temporal generalizations known. Under the scenario of sequential measurements performed on a single quantum system, semi-definite optimization-based techniques have been applied to bound sequential measurement inequalities. Building upon this formalism, we show that the optimizer matrix that saturates such sequential inequalities is unique and, moreover, this uniqueness is robust to small deviations from the quantum bound. Furthermore, we consider a generalized scenario in the presence of quantum channels and highlight analogies to the structure of Bell and sequential inequalities using the pseudo-density matrix formalism. These analogies allow us to show a practical use of maximal violations of sequential inequalities in the form of certification of quantum channels up to isometries.more » « lessFree, publicly-accessible full text available December 1, 2025
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The calculation of off-diagonal matrix elements has various applications in fields such as nuclear physics and quantum chemistry. In this paper, we present a noisy intermediate scale quantum algorithm for estimating the diagonal and off-diagonal matrix elements of a generic observable in the energy eigenbasis of a given Hamiltonian without explicitly preparing its eigenstates. By means of numerical simulations we show that this approach finds many of the matrix elements for the one and two qubits cases. Specifically, while in the first case, one can initialize the ansatz parameters over a broad interval, in the latter the optimization landscape can significantly slow down the speed of convergence and one should therefore be careful to restrict the initialization to a smaller range of parameters.more » « less
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Abstract Self-testing allows one to characterise quantum systems under minimal assumptions. However, existing schemes rely on quantum nonlocality and cannot be applied to systems that are not entangled. Here, we introduce a robust method that achieves self-testing of individual systems by taking advantage of contextuality. The scheme is based on the simplest contextuality witness for the simplest contextual quantum system—the Klyachko-Can-Binicioğlu-Shumovsky inequality for the qutrit. We establish a lower bound on the fidelity of the state and the measurements as a function of the value of the witness under a pragmatic assumption on the measurements. We apply the method in an experiment on a single trapped40Ca+using randomly chosen measurements and perfect detection efficiency. Using the observed statistics, we obtain an experimental demonstration of self-testing of a single quantum system.more » « less
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